Datsyuk will replace Phoenix's injured Krystofer Kolanos in the YoungStars game on Friday night. Chelios will join Shanahan on the North American All-Star roster, taking the place of New Jersey's injured Brian Rafalski.
Datsyuk said it was "very exciting news" through interpreter Sergei Fedorov.
The 40-year-old Chelios will be making his 11th All-Star appearance. "I've always enjoyed going, and obviously, I don't have too many left," he said.
All-Star Weekend is this weekend, starting with the YoungStars Game taking place Friday night and concluding with the All-Star Game on Saturday afternoon.
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